Pd-catalyzed desulfitative Hiyama coupling with sulfonyl chlorides

被引:27
|
作者
Zhang, Wei [1 ]
Liu, Fang [2 ]
Li, Ke [3 ]
Zhao, Baoli [4 ,5 ]
机构
[1] Xinxiang Univ, Dept Chem & Chem Engn, Xinxiang 453003, Henan Province, Peoples R China
[2] Hebei North Univ, Life Sci Res Ctr, Zhangjiakou 075000, Hebei Province, Peoples R China
[3] Jiaozuo City Environm Protect Bur, Jiaozuo 453003, Henan Province, Peoples R China
[4] Shaoxing Univ, Inst Appl Chem, Shaoxing 312000, Zhejiang, Peoples R China
[5] Shaoxing Univ, Dept Chem, Shaoxing 312000, Zhejiang, Peoples R China
关键词
Pd-catalyzed; desulfitative coupling; Hiyama cross-coupling; arylsulfonyl chloride; CROSS-COUPLINGS; ARYLSULFONYL CHLORIDES; ARENESULFONYL CHLORIDES; ARYL BROMIDES; MECHANISMS; REAGENTS; STILLE;
D O I
10.1002/aoc.3139
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Palladium-catalyzed desulfitative Hiyama cross-coupling reactions of various arylsulfonyl chlorides with aryltriethoxysilane have been achieved in good yields. The reported cross-coupling reactions are tolerant to the common functional groups regardless of electron-withdrawing or electron-donating, making these transformations attractive alternatives to the traditional cross-coupling approaches. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码:379 / 381
页数:3
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