Kinetics of cotelomerization of 3-(trimethoxysilyl)propyl methacrylate and perfluorodecylacrylate

被引：15

作者：

Pardal, Francis ^{[1
]}

Lapinte, Vincent ^{[1
]}

Robin, Jean-Jacques ^{[1
]}

机构：

[1] Univ Montpellier 2, Inst Charles Gerhardt Montpellier, Equipe Ingn & Architectures Macromol, CNRS UM2 ENSCM UM1,UMR5253, F-34095 Montpellier 5, France

来源：

EUROPEAN POLYMER JOURNAL | 2009年 / 45卷 / 04期

关键词：

Copolymerization; Fluorinated polyacrylate; Kinetic; Reactivity ratio; Telomerization; METHYL-METHACRYLATE; THIOGLYCOLIC ACID; ACRYLIC-ACID; RADICAL COPOLYMERIZATION; VINYLIDENE FLUORIDE; TELOMERIZATION; POLYMERIZATION; NANOPARTICLES; MONOMER; STYRENE;

D O I：

10.1016/j.eurpolymj.2008.12.035

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The telomerization of 3-(trimethoxysilyl)propyl methacrylate (TMSPMA) in the presence of 2-mercaptoethanol was investigated at 80 degrees C in acetonitrile. In our case, the efficiency of 2-mercaptoethanol as telogen agent, with TMSPMA, was demonstrated and the transfer constant (C-T) was determined. Moreover, cotelomerization of TMSPMA with perfluorodecylacrylate (PFDA) using various PFDA contents was investigated in order to obtain alpha-hydroxy oligomers with statistical copolymer-type main chains bearing trimethoxysilyl and perfluoro pendant chains. Until 10 mol% PFDA, no phase separation occured. In this composition, r(TMSPMA) and r(PFDA) reactivity ratios were calculated, thus showing a tendency for a statistical distribution of the monomer units in the copolymer. (c) 2008 Elsevier Ltd. All rights reserved.

引用

页码：1198 / 1207

页数：10

共 50 条

[1] Kinetics of cotelomerization of 3-(trimethoxysilyl)propyl methacrylate and perfluorodecylacrylate
Pardal, Francis
Lapinte, Vincent
Robin, Jean-Jacques
European Polymer Journal, 2009, 45 (04): : 1198 - 1207
[2] Surfactant-Stabilized Spontaneous 3-(Trimethoxysilyl) Propyl Methacrylate Nanoemulsions
Neibloom, Denise
Bevan, Michael A.
Frechette, Joelle
LANGMUIR, 2020, 36 (01) : 284 - 292
[3] Toward Hybrid Materials: Group Transfer Polymerization of 3-(Trimethoxysilyl)propyl Methacrylate
Chung, Justin J.
Jones, Julian R.
Georgiou, Theoni K.
MACROMOLECULAR RAPID COMMUNICATIONS, 2015, 36 (20) : 1806 - 1809
[4] Kaolinite-polymer compounds by grafting of 2-hydroxyethyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate
Ferreira, Breno F.
Ciuffi, Katia J.
Nassar, Eduardo J.
Vicente, Miguel A.
Trujillano, Raquel
Rives, Vicente
de Faria, Emerson H.
APPLIED CLAY SCIENCE, 2017, 146 : 526 - 534
[5] Modification of Titanium Dioxide Nanoparticles with 3-(Trimethoxysilyl)propyl Methacrylate Silane Coupling Agent
Nguyen, Thuy-Chinh
Nguyen, Tien-Dung
Vu, Duc-Toan
Dinh, Duc-Phuong
Nguyen, Anh-Hiep
Ly, Thi-Ngoc-Lien
Dao, Phi-Hung
Nguyen, Thi-Len
Bach, Long-Giang
Thai, Hoang
JOURNAL OF CHEMISTRY, 2020, 2020
[6] Atom-transfer radical polymerization of a reactive monomer: 3-(Trimethoxysilyl)propyl methacrylate
Du, JZ
Chen, YM
MACROMOLECULES, 2004, 37 (17) : 6322 - 6328
[7] Modification of Poly (vinylidene fluoride) by Grafting of Functional Monomer 3-(Trimethoxysilyl)propyl Methacrylate
Liu, Lina
Chen, Yingbo
Zhang, Yufeng
ADVANCED POLYMER SCIENCE AND ENGINEERING, 2011, 221 : 32 - 36
[8] The Effect of 3-(Trimethoxysilyl) Propyl Methacrylate on the Mechanical, Thermal, and Morphological Properties of Poly(methyl methacrylate)/Hydroxyapatite Composites
Tham, W. L.
Chow, W. S.
Ishak, Z. A. Mohd
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 118 (01) : 218 - 228
[9] Phase behavior for the 2-(trimethylsilyloxy)ethyl methacrylate and 3-(trimethoxysilyl)propyl methacrylate in supercritical carbon dioxide
Lee, Bong-Seop
Lee, Jae-Kyung
Bong, Jae-Hwi
Byun, Hun-Soo
FLUID PHASE EQUILIBRIA, 2018, 462 : 1 - 5
[10] Synthesis and characterization of microencapsulated n-octadecane with hybrid shells containing 3-(trimethoxysilyl) propyl methacrylate and methyl methacrylate
Gang Li
Wenhong Li
Journal of Thermal Analysis and Calorimetry, 2017, 129 : 915 - 924

← 1 2 3 4 5 →