Tuning Plasmon Resonance of Gold Nanostars for Enhancements of Nonlinear Optical Response and Raman Scattering

Localized surface plasmon resonances (LSPRs) of metal nanostructures are highly related to the shape, which could greatly enhance the light matter interaction at nanoscale. Here, we investigate the LSPRs of gold nanostars corresponding to the unique morphology and demonstrate surface-enhanced Raman scattering (SERS) activities and nonlinear refraction properties of two typical structures. By adjusting the synthesis condition, the main plasmon resonance could be tuned from 557 to 760 nm. The plasmon modes and intense field enhancement near the sharp tips are revealed by finite-difference timed-domain (FDTD) simulations. The nonlinear refractive index vertical bar gamma vertical bar reaches to the maximum value when the excitation wavelength is resonant to the LSPRs wavelength. The maximum value of vertical bar gamma vertical bar for long-branched nanostars (lambda(SP) = 706 nm) is 5.843 x 10(-4) cm(2)/GW, which is about 1.5 times larger than that of spherical-like nanostars with lambda(SP) = 563 nm. The SERS activity of long-branched nanostars is about 15 times larger than that of spherical-like gold nanostars.