Close-Packed Superlattices of Side-by-Side Assembled Au-CdSe Nanorods

被引:110
|
作者
Zhao, Nana [1 ]
Liu, Kun [1 ]
Greener, Jesse [1 ]
Nie, Zhihong [1 ,2 ]
Kumacheva, Eugenia [1 ,3 ,4 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
[2] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA
[3] Univ Toronto, Inst Biomat & Biomed Engn, Toronto, ON M5S 3G9, Canada
[4] Univ Toronto, Dept Chem Engn & Appl Chem, Toronto, ON M5S 3E5, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
NANOPARTICLES; NANOCRYSTALS; MONOLAYERS; GROWTH;
D O I
10.1021/nl901567a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report solution-based side-by-side self-assembly of Au-tipped CdSe nanorods (NRs) In large two-dimensional superlattices and the deposition of these lattices on a substrate with NRs aligned perpendicular to the surface. The side-by-side assembly of the NRs was triggered by changing the solvent quality for the ligands coating the long side of the nanorods. The stability of the self-assembled superlattices was enhanced due to the hydrogen bonding between the ligands attached to the Au tips of the nanorods. The reported approach can further facilitate the hierarchical integration of multicomponent NRs into functional devices.
引用
收藏
页码:3077 / 3081
页数:5
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