Dimephosphone analogs: II. Dialkyl(diaryl)-(2-methyl-4-oxopent-2-yl)phosphine Oxide Oximes: Synthesis, Structure, and Generation of Iminoxyl Radicals

被引：4
|
作者：
Tatarinov, D. A. [1 ]
Mironov, V. F. [1 ]
Kostin, A. A. [1 ]
Mironova, E. V. [1 ]
Krivolapov, D. B. [1 ]
Morozov, V. I. [1 ]
Nabiullin, V. N. [1 ]
Il'yasov, A. V. [1 ]
Buzykin, B. I. [1 ]
机构：
[1] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan 420088, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2014年 / 84卷 / 05期
基金：
俄罗斯基础研究基金会;
关键词：
PARAMAGNETIC-RESONANCE SPECTROSCOPY; 2-OXIDE;
D O I：
10.1134/S107036321405020X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dialkyl(diaryl)-(2-methyl-4-oxopent-2-yl)phosphine oxide oximes have been synthesized for the first time. According to the X-ray diffraction data, these compounds in crystal exist as a single E isomer. Their structure in solution and the E/Z isomer ratio were determined by H-1 and C-13 NMR spectroscopy.
引用
收藏
页码：901 / 910
页数：10
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