Graphite intercalation compounds prepared in solutions of alkali metals in 2-methyltetrahydrofuran and 2,5-dimethyltetrahydrofuran

被引：62

作者：

Mizutani, Y ^{[1
]}

Abe, T ^{[1
]}

Ikeda, K ^{[1
]}

Ihara, E ^{[1
]}

Asano, M ^{[1
]}

Harada, T ^{[1
]}

Inaba, M ^{[1
]}

Ogumi, Z ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH ENGN,SAKYO KU,KYOTO 60601,JAPAN

来源：

CARBON | 1997年 / 35卷 / 01期

关键词：

intercalation compounds; natural graphite; X-ray diffractions;

D O I：

10.1016/S0008-6223(96)00127-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The intercalation of alkali metals (Li, K, Rb and Cs) into natural graphite flakes in the solutions of 2-methyltetrahydrofuran (MeTHF) and 2, 5-dimethyltetrahydrofuran (diMeTHF) containing naphthalene has been studied by X-ray diffraction (XRD), where naphthalene is used as a dissolving agent for alkali metals. When MeTHF is used as a solvent, binary Li- and K-graphite intercalation compounds (GICs) have been obtained, in contrast to the case of Rb and Cs, where both binary alkali metal GICs and ternary alkali metal-MeTHF-GICs are obtained. Using diMeTHF instead of MeTHF, a selective preparation of binary GICs for all the alkali metals has been established. Copyright (C) 1997 Elsevier Science Ltd.

引用

页码：61 / 65

页数：5

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