An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

被引：115

作者：

Arceo, Elena ^{[1
]}

Marsden, Peter ^{[1
]}

Bergman, Robert G. ^{[1
,2
]}

Ellman, Jonathan A. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 23期

关键词：

ALLYL ALCOHOL; TRANSFORMATION; CHEMICALS; CATALYST; ACROLEIN; DIOLS;

D O I：

10.1039/b907746d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient 1,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass-derived polyols (glycerol and erythritol) that results in the conversion of the 1,2-dihydroxy group to a carbon-carbon double bond.

引用

页码：3357 / 3359

页数：3

共 8 条

[1] A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid
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