Separation of carrier-free 90Y from high level waste by extraction chromatographic technique using 2-ethylhexyl-2-ethylhexyl phosphonic acid (KSM-17)

被引：26

作者：

Achuthan, PV ^{[1
]}

Dhami, PS ^{[1
]}

Kannan, R ^{[1
]}

Gopalakrishnan, V ^{[1
]}

Ramanujam, A ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Bombay 400085, Maharashtra, India

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2000年 / 35卷 / 02期

关键词：

D O I：

10.1081/SS-100100155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An extraction chromatographic technique has been developed for the separation of carrier-free Y-90 from the Sr-90 present in the high level waste (HLW) of the Purex process. When a Purex HLW solution in 2-3 M HNO3 is passed through a CMPO-Chromosorb-102 (CAC) column, all the trivalent, tetravalent, and hexavalent ions are sorbed. The effluent from this experiment, after adjusting the pH to 2 with NaOH, was passed through a 2-ethylhexyl-2-ethylhexyl phosphonic acid (KSM-17)-Chromosorb-102 (KSMC) extraction chromatographic column where only Y-90 was sorbed. All the other ions (Sr-90, Cs-137, Sb-125, Ru-106, Rh-106, etc.) were washed off with dilute HNO3 (pH 2), and carrier-free Y-90 was eluted with 0.5 M HNO3. This technique can yield Y-90 in mCi levels in pure form for medical applications. The Sr-90 can be used repeatedly after allowing for Y-90 buildup.

引用

页码：261 / 270

页数：10

共 18 条

[1] Separation of carrier-free 90Y from high level waste by supported liquid membrane using KSM-17
A. Ramanujam
P. V. Achuthan
P. S. Dhami
R. Kannan
V. Gopalakrishnan
V. P. Kansra
R. H. Iyer
K. Balu
Journal of Radioanalytical and Nuclear Chemistry, 2001, 247 : 185 - 191
[2] Separation of carrier-free 90Y from high level waste by supported liquid membrane using KSM-17
Ramanujam, A
Achuthan, PV
Dhami, PS
Kannan, R
Gopalakrishnan, V
Kansra, VP
Iyer, RH
Balu, K
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2001, 247 (01) : 185 - 191
[3] Studies on the development of a two stage SLM system for the separation of carrier-free 90Y using KSM-17 and CMPO as carriers
Dhami, P. S.
Naik, P. W.
Dudwadkar, N. L.
Kannan, R.
Achuthan, P. V.
Moorthy, A. D.
Jambunathan, U.
Munshi, S. K.
Dey, P. K.
Pandey, Usha
Venkatesh, Meera
SEPARATION SCIENCE AND TECHNOLOGY, 2007, 42 (05) : 1107 - 1121
[4] Separation of Carrier Free 90Y from 90Sr by Hollow Fiber Supported Liquid Membrane Containing Bis(2-ethylhexyl) Phosphonic Acid
Kandwal, Pankaj
Ansari, Seraj A.
Mohapatra, Prasanta K.
Manchanda, Vijay K.
SEPARATION SCIENCE AND TECHNOLOGY, 2011, 46 (06) : 904 - 911
[5] Extraction chromatographic separation of carrier-free 90Y from 90Sr/90Y generator by crown ether coated silica gels
Chuang, J.T.
Lo, J.G.
Journal of Radioanalytical and Nuclear Chemistry, 1996, 204 (01): : 83 - 93
[6] Extraction chromatographic separation of carrier-free 90Y from 90Sr/90Y generator by crown ether coated silica gels
J Radioanal Nucl Chem, 1 (83):
[7] Separation of Carrier-Free 90Y from 90Sr by SLM Technique Using D2EHPA in N-Dodecane as Carrier
Naik, P. W.
Jagasia, Poonam
Dhami, P. S.
Achuthan, P. V.
Tripathi, S. C.
Munshi, S. K.
Dey, P. K.
Venkatesh, Meera
SEPARATION SCIENCE AND TECHNOLOGY, 2010, 45 (04) : 554 - 561
[8] Selective extraction and separation of titanium(IV) from multivalent metal chloride solutions using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester
Saji, J
Reddy, MLP
SEPARATION SCIENCE AND TECHNOLOGY, 2003, 38 (02) : 427 - 441
[9] Solvent extraction separation of vanadium(V) from multivalent metal chloride solutions using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester
Jayadas, S
Reddy, ML
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2002, 77 (10) : 1149 - 1156
[10] Kinetics and mechanism of Yb(III) extraction and separation from Y(III) with mixtures of bis(2,4,4-trimethylpentyl)phosphinic acid and 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester
Xiong, Y
Li, W
Wu, DB
Li, DQ
Meng, SL
SEPARATION SCIENCE AND TECHNOLOGY, 2006, 41 (01) : 167 - 178

← 1 2 →