An iridaborane reaction cycle driven by PMe3 and BH3•THF:: Synthesis and characterization of [CpIrB3H7(PMe3)] and [CpIrB2H6(PMe3)]

被引：0

作者：

Macías, R ^{[1
]}

Fehlner, TP ^{[1
]}

Beatty, AM ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 20期

关键词：

boranes; cluster compounds; reaction cycles; transition metals;

D O I：

10.1002/1521-3773(20021018)41:20<3860::AID-ANIE3860>3.0.CO;2-S

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction cycles of clusters: [Cp*IrB3H9] and [Cp*IrB4H10] react with PMe3 to give cleavage products that undergo addition of borane to reconstruct the parent clusters. Overall, a new reaction cycle is formed, comprising two reversible and two irreversible steps, which involve the formation of new phosphane-substituted iridaboranes (see scheme).

引用

页码：3860 / 3862

页数：3

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An iridaborane reaction cycle driven by PMe3 and BH3•THF:: Synthesis and characterization of [Cp*IrB3H7(PMe3)] and [Cp*IrB2H6(PMe3)]

An iridaborane reaction cycle driven by PMe3 and BH3•THF:: Synthesis and characterization of [CpIrB3H7(PMe3)] and [CpIrB2H6(PMe3)]