Preparation of SWNTs/Pt Composites Using SWNTs as Reducing Agent and Their Catalytic Properties

被引：0
|
作者：
Cao You-Ming [1 ,3 ]
Wang Zhi-Yong [1 ]
Niu Fang
Song Wei-Guo [2 ]
Shi Zu-Jin [1 ]
Gu Zhen-Nan [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[3] Chongqing Univ Arts & Sci, Coll Chem & Environm Engn, Yongcuhan 402168, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2009年 / 30卷 / 04期
关键词：
Single-wall carbon nanotube; Composite; Pt; Catalytic property; WALLED CARBON NANOTUBES; PLATINUM; PURIFICATION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
SWNTs/Pt composites for catalysis were prepared through redox reaction between SWNTs and K2PtCl6. Characterization of the composites by TEM, XPS and TG techniques revealed that large quantities of Pt particles with diameters of similar to 1.5 nm distribute evenly on the SWNTs. The influences of concentration of K2PtCl6 solution and solvents of SWNTs on the quantity and size of Pt particles were investigated. SWNTs/Pt composites containing 24.76% (mass fraction) Pt were obtained using high purity SWNTs and K2PtCl6 solution of 10 mmol/L. The SWNTs/Pt composites exhibit high catalytic activity for hydrogenation of cyclohexene. The conversion rate from cyclohexene to cyclohexane is up to 100% at room temperature.
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页码：741 / 745
页数：5
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