A water-based room temperature synthesis of ZIF-93 for CO2 adsorption

被引：54

作者：

Ramos-Fernandez, E. V. ^{[1
]}

Grau-Atienza, A. ^{[1
]}

Farrusseng, D. ^{[2
]}

Aguado, S. ^{[3
]}

机构：

[1] Univ Alicante, Dept Inorgan Chem, Alicante, Spain

[2] Univ Lyon 1, CNRS, Inst Rech Catalyse & Environm Lyon IRCELYON, Villeurbanne, France

[3] Univ Alcala, Dept Chem Engn, Alcala De Henares, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2018年 / 6卷 / 14期

关键词：

METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE CAPTURE; SELECTIVE CAPTURE; FUNCTIONALITY;

D O I：

10.1039/c7ta09807c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zeolitic imidazolate framework ZIF-93 was synthesized from a stoichiometric mixture of metal-ligand in aqueous solutions at room temperature, yielding 80% of pure product. The characterization of the material confirmed the formation of a material having the same properties as the one obtained previously by a solvothermal method in the DMF route. This method is very promising for the efficient and environmentally friendly synthesis of ZIFs for CO2 capture application, proved by breakthrough experiments of binary CO2/N-2 mixtures.

引用

页码：5598 / 5602

页数：5

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