Ruthenium(III) bis-bidentate Schiff base complexes mediated transfer hydrogenation of imines

被引：43

作者：

Venkatachalam, GaImari ^{[1
]}

Ramesh, Rengan ^{[1
]}

机构：

[1] Bharathidasan Univ, Sch Chem, Tiruchirappalli 620024, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 07期

关键词：

N; O donors; Ru(III) bis-bidentate Schiff base complexes; spectral studies; transfer hydrogenation of imines;

D O I：

10.1016/j.inoche.2006.04.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mono anionic bidentate Schiff base ligands of N, O bonding system has been employed to synthesize a series of new stable ruthenium(III) complexes of general composition [RuX(EPh3)(L)(2)] (where, E = P or As, X = Cl or Br and L = O, N donor of Schiff bases). All the complexes have been fully characterized by elemental analyses, magnetic susceptibility measurements, FT-IR, UV-Vis, EPR and cyclic voltammetric techniques. The catalytic reactivity explored proving these complexes to be efficient in the transfer hydrogenation of imines to amines with moderate to high conversions. (C) 2006 Elsevier B.V, All rights reserved.

引用

页码：703 / 707

页数：5