Thermodynamics of binary mixture glasses

被引:91
作者
Coluzzi, B
Mézard, M
Parisi, G
Verrocchio, P
机构
[1] Forschungszentrum Julich, John von Neumann Inst Comp, D-52425 Julich, Germany
[2] Univ Calif Santa Barbara, Inst Theoret Phys, Santa Barbara, CA 93106 USA
[3] CNRS, Phys Theor ENS, Paris, France
[4] Univ Roma La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[5] Univ Roma La Sapienza, Sez INFN, I-00185 Rome, Italy
关键词
D O I
10.1063/1.480246
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We compute the thermodynamic properties of the glass phase in a binary mixture of soft spheres. Our approach is a generalization to mixtures of the replica strategy, recently proposed by Mezard and Parisi, providing a first principle statistical mechanics computation of the thermodynamics of glasses. The method starts from the interatomic potentials, and translates the problem into the study of a molecular liquid. We compare our analytical predictions to numerical simulations, focusing onto the values of the thermodynamic transition temperature and the configurational entropy. (C) 1999 American Institute of Physics. [S0021- 9606(99)51443-8].
引用
收藏
页码:9039 / 9052
页数:14
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