Colloidal Ag2S/SiO2 core/shell quantum dots with IR luminescence

This paper presents the results of studies of the luminescent properties for colloidal Ag2S quantum dots, coated with SiO2 shell, carried out by techniques of transmission electron microscopy, optical absorption and luminescence spectroscopy time correlated single photon counting, quantum yield of luminescence. Various approaches to the formation of SiO2 shell is analyzed. It is concluded that an increase in the quantum yield of Ag2S QDs luminescence in the condition of the formation of a SiO2 shell on the interfaces provides the passivation of dangling bonds and localization of charge carriers in the nucleus. It is shown that, under the considered conditions for the synthesis of Ag2S/SiO2 core/shell structures in ethylene glycol, the use of TEOS as a precursor for SiO2 shell provides the formation of a less defective shell, leading to an increase in the quantum yield of luminescence from 1.6% to 8%. On the contrary, the use of sodium metasilicate and high concentrations of MPTMS does not ensure the formation of a dense SiO2 shell of several monolayers thickness on Ag2S interfaces, coated with 2-mercaptopropionic acid. (C) 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement