Chemoselective reduction of nitroaromatics to anilines using decaborane in methanol

被引：51
|
作者：
Bae, JW
Cho, YJ
Lee, SH
Yoon, CM [1 ]
机构：
[1] Korea Univ, Grad Sch Biotechnol, Dept Life Sci & Biotechnol, Seoul 136701, South Korea
[2] Korea Univ, Grad Sch Chem, Dept Chem, Seoul 136701, South Korea
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 02期
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1016/S0040-4039(99)02048-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Nitrobenzenes were chemoselectively reduced to the corresponding anilines using decaborane (B10H14) in the presence of Pd/C and two drops of acetic acid at reflux under nitrogen atmosphere in high yields. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：175 / 177
页数：3
相关论文
共 50 条
  • [1] Metal-free chemoselective reduction of nitroaromatics to anilines via hydrogen transfer strategy
    Shuai, Qi
    Li, Jun
    Zhao, Feng
    Su, Weike
    Deng, Guojun
    CHEMICAL PAPERS, 2019, 73 (04): : 965 - 975
  • [2] Metal-free chemoselective reduction of nitroaromatics to anilines via hydrogen transfer strategy
    Qi Shuai
    Jun Li
    Feng Zhao
    Weike Su
    Guojun Deng
    Chemical Papers, 2019, 73 : 965 - 975
  • [3] Chemoselective reduction of aldehydes using decaborane in aqueous solution
    Lee, Seung Hwan
    Nam, Mi Hye
    Cho, Min Young
    Yoo, Byung Woo
    Rhee, Hak June
    Yoon, Cheol Min
    SYNTHETIC COMMUNICATIONS, 2006, 36 (17) : 2469 - 2474
  • [4] A practical and chemoselective reduction of nitroarenes to anilines using activated iron
    Liu, YG
    Lu, YS
    Prashad, M
    Repic, J
    Blacklock, TJ
    ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (2-3) : 217 - 219
  • [5] Ultrasound-assisted rapid reduction of nitroaromatics to anilines using gallium metal
    Bento, Ian
    Bernaldez, Mabel
    Noguchi, Ryden
    Kawakami, Joel
    SYNTHETIC COMMUNICATIONS, 2020, 50 (09) : 1404 - 1407
  • [6] Photocatalytic reduction of nitroaromatics into anilines using CeO2-TiO2 nanocomposite
    Lu, Caiyun
    Yin, Zhengfeng
    Sun, Chengxin
    Chen, Changdong
    Wang, Fangfang
    MOLECULAR CATALYSIS, 2021, 513
  • [7] Reductive methylation using decaborane in methanol
    Jung, YJ
    Bae, JW
    Yoon, COM
    Yoo, BW
    Yoon, CM
    SYNTHETIC COMMUNICATIONS, 2001, 31 (22) : 3417 - 3421
  • [8] Reduction of ketones to alcohols using a decaborane/pyrrolidine/cerium(III) chloride system in methanol
    Bae, JW
    Lee, SH
    Jung, YJ
    Yoon, COM
    Yoon, CM
    TETRAHEDRON LETTERS, 2001, 42 (11) : 2137 - 2139
  • [9] Hydrogenation of alkenes or alkynes using decaborane in methanol
    Lee, SH
    Park, YJ
    Yoon, CM
    TETRAHEDRON LETTERS, 2000, 41 (06) : 887 - 889
  • [10] A reductive amination of carbonyls with amines using decaborane in methanol
    Bae, Jong Woo
    Lee, Seung Hwan
    Cho, Young Jin
    Yoon, Cheol Min
    Journal of the Chemical Society, Perkin Transactions 1, 2000, (02): : 145 - 146
12345