Is the Volume-Based Thermodynamics (VBT) Approach Valid for the Estimation of the Lattice Enthalpy of Salts Containing the 5,5′-(Tetrazolate-1N-oxide) Dianion?

被引：15

作者：

Glasser, Leslie ^{[1
]}

Jenkins, H. Donald B. ^{[2
]}

Klapoetke, Thomas M. ^{[3
,4
]}

机构：

[1] Curtin Univ, Nanochem Res Inst, Dept Chem, Perth, WA 6845, Australia

[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

[3] Univ Munich, Dept Chem, D-81377 Munich, Germany

[4] Univ Maryland UMD, Ctr Energet Concepts Dev CED, Dept Mech Engn, College Pk, MD 20742 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 07期

关键词：

Explosives; Lattice enthalpy; Tetrazole; TKX-50; Volume-based thermodynamics (VBT); COMPLEX-IONS; ENERGIES;

D O I：

10.1002/zaac.201400007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In previous publications we have used volume-based thermodynamics (VBT) to estimate the lattice energies and enthalpies of new high-energy ionic materials. The use of the VBT approach for salts containing non-spherical ions such as the 5,5'-(tetrazolate-1N-oxide) dianion in TKX-50 [bishydroxylammonium 5,5'-(tetrazolate-1N-oxide)] has received some criticism. Herein we show that the VBT approach is suitable for the estimation of lattice energies/enthalpies for such salts.

引用

页码：1297 / 1299

页数：3