Preparation, spectroscopic characterization and crystal structures of mercury(II)bis(tetracyanoborate) Hg[B(CN)4]2 and dimercury(I)-bis(tetracyanoborate) Hg2[B(CN)4]2

被引：0

作者：

Berkei, M

Bernhardt, E

Schürmann, M

Mehring, M

Willner, H

机构：

[1] Univ Duisburg Gesamthsch, Inst Chem, Fak 4, D-47048 Duisburg, Germany

[2] Univ Dortmund, Fachbereich Chem, D-4600 Dortmund, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 08期

关键词：

mercury; tetracyanoborates; structure elucidation; vibrational spectroscopy;

D O I：

10.1002/1521-3749(200208)628:8<1734::AID-ZAAC1734>3.0.CO;2-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hg[B(CN)(4)](2) (1) is synthesised by the reaction between Hg(NO3)(2) and K[B(CN)(4)](2). In a comproportionation reaction of 1 with elemental mercury the corresponding mercury(I) salt Hg-2[B(CN)(4)](2) (2) is obtained. The compounds were characterised by vibrational- and NMR-spectroscopy, and their crystal structures were determined. Hg[B(CN)(4)](2) crystallizes in the trigonal system in the space group Oral with a = 781.75(3) pm, c = 601.68(2) pm, V = 318.44(2) Angstrom(3), and one formula unit per unit cell. For Hg-2[B(CN)(4)](2) an orthorhombic unit cell with a = 568.9(1) pm, b = 3280.9(7) pm, c = 601.68(2) pm, V = 1389.6(5) Angstrom, and Z = 4 is observed.

引用

页码：1734 / 1740

页数：7

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