Nucleophilic imidoesterification of dicarbonyl compounds with cyanatobenzenes through C-C bond formation

被引：4

作者：

Ma, Hang ^{[1
]}

He, Yang ^{[1
]}

Huang, Ruo-Feng ^{[1
]}

Zhang, Xiao-Hui ^{[1
]}

Pan, Jing ^{[1
]}

Li, Jia-Qiang ^{[1
]}

He, Chao ^{[1
]}

Ling, Xue-Ge ^{[1
]}

Wang, Xuan-Lun ^{[3
]}

Xiong, Yan ^{[1
,2
]}

机构：

[1] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400044, Peoples R China

[2] Chongqing Univ, Chongqing Key Lab Chem Proc Clean Energy & Resour, Chongqing 400044, Peoples R China

[3] Chongqing Univ Technol, Coll Mat Sci & Engn, Chongqing 400054, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2014年 / 25卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Imidoesters; Cyanatobenzenes; Dicarbonyl compounds; Imidoesterification; Nucleophilic addition; CYANATION; RADICALS; ESTERS;

D O I：

10.1016/j.cclet.2014.06.008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under neat conditions, an efficient method for synthesis of imidoesters has been developed using cyanatobenzenes and dicarbonyl compounds. Nucleophilic addition spontaneously occurred between the two kinds of materials at room temperature with yields of up to 90%. A mechanism directed towards to the imidoester formation has been proposed. (C) 2014 Yan Xiong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：1327 / 1330

页数：4

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