Synthesis and Structure of an Inorganic-organic Hybrid Zinc Phosphite

被引：2
|
作者：
Wang Xuelei [1 ]
Yan Yan [1 ]
Wu Junbiao [1 ]
Zou Yongcun [1 ]
Zhang Chuanqi [1 ]
Li Jiyang [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2014年 / 35卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Zinc phosphite; Inorganic-organic hybrid compound; Hydrothermal synthesis; 24-RING CHANNELS; FRAMEWORK; TRANSFORMATION; NETWORKS; ZEOLITE;
D O I：
10.7503/cjcu20131279
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D inorganic-organic hybrid zinc phosphite (C6N2H16)(0.5)ZnHPO3 (ZnHPO-CJ15) has been hydrothermally synthesized. Crystal data for ZnHPO-CJ15 are as follows monoclinic system, P2(1)/c space group, a = 1. 19587 nm, b = 0. 82766 ( 5) nm, c = 0. 77756 (5) nm, alpha = 90. 00 degrees, beta = 95. 8370 (10)degrees, gamma = 90. 00 degrees, V=0. 76562(8) nm(3) and Z =1. Single-crystal structure analysis reveals that the inorganic framework of ZnHPO-CJ15 is constructed by the connection of HPO3 pseudo-pyramids and ZnO3N tetrahedral to form 2D layers with 4- and 8-rings. The 1,6-hexanediamine molecules act as the pillars to link the adjacent zinc phosphite layers via N-Zn bonds to form 3D framework.
引用
收藏
页码：1142 / 1145
页数：4
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