A solvothermal approach for the size-, shape- and phase-controlled synthesis and properties of CuInS2

In this work, Copper Indium disulfide (CIS) nanoparticles of size similar to 5 nm were prepared via solvothermal approach in ethanol under the nitrogen atmosphere using copper chloride, indium chloride and thiourea (Tu) as starting materials, without any assistance through organic ligands at the reaction temperature of 150 degrees C. The factors which might affect the morphology, structure, phase of the product during the synthesis were discussed. It was found that the products were significantly affected by the reaction time and solvent. The morphology, structure, phase constituents and optical properties of the as prepared CIS powders were characterized by X-ray diffraction (XRD), Energy dispersive Spectroscopy (EDS), scanning electron microscopy (SEM) and ultraviolet-visible (UV-Vis) spectrometry respectively. The result shows that the CIS nanoparticles can be synthesized by solvothermal method at a reaction time of 2 h and shows that when the reaction time was increased from 2 h to 48 h, CIS porous flower like nanoparticles were obtained as we increase the reaction time. We also observed that in this process, the phase selection of WZ-CIS or CH-CIS is greatly influence by solvent. We also observed that, in this process sulfur source did not influence the phase but participated in the growth of the nanoparticles. (C) 2013 Elsevier B.V. All rights reserved.