A biphenyl containing two electron-donating and two electron-accepting moieties: a rigid and small donor-acceptor-donor ladder system

被引:25
|
作者
Greulich, Tobias W. [1 ]
Suzuki, Naoya [2 ,3 ]
Daniliuc, Constantin G. [1 ]
Fukazawa, Aiko [2 ,3 ]
Yamaguchi, Eriko [2 ,3 ]
Studer, Armido [1 ]
Yamaguchi, Shigehiro [2 ,3 ]
机构
[1] Univ Munster, Corrensstr 40, D-48149 Munster, Germany
[2] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Chikusa Ku, Nagoya, Aichi 4648602, Japan
关键词
PI-CONJUGATED MATERIALS; ORGANIC SEMICONDUCTORS; DERIVATIVES; PHOSPHAVIOLOGENS; TRANSISTORS; PHOSPHORUS; PHOSPHANES; DESIGN; ROUTE; ALKYL;
D O I
10.1039/c5cc03063c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ladder pi-conjugated materials and also push-pull systems belong to important classes of compounds for the development of organic electronic devices. In this communication, a novel pi-conjugated material that unifies the properties of both of these classes is presented. The material comprises a rigid biphenyl framework, which bears two bridging electron-accepting phosphine oxide moieties as well as two electron-donating amino groups. The structure and photophysical properties of this compound are discussed and compared with those of a related system lacking the second P-moiety.
引用
收藏
页码:2374 / 2377
页数:4
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