Electrical Conductivity of the Ammonia-Water System

被引:12
|
作者
Shcherbakov, V. V. [1 ]
Artemkina, Yu. M. [1 ]
Ponomareva, T. N. [1 ]
Kirillov, A. D. [2 ]
机构
[1] Mendeleev Univ Chem Technol, Moscow 125190, Russia
[2] Moscow State Open Univ, Moscow 129805, Russia
关键词
Electrical Conductivity; Water System; Ammonia Concentration; Aqueous Ammonia; Intermolecular Association;
D O I
10.1134/S0036023609020193
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The electrical conductivity (EC) of the ammonia-water system was studied in the concentration range 0.1-10 mol/L ammonia and the temperature range 15-60 degrees C. The maximal EC of aqueous ammonia at a given temperature is proposed as the parameter for generalizing experimental results. The normalized EC was calculated as the ratio of the EC of aqueous ammonia of a given concentration to the maximal EC at a given temperature. Over the ranges of the concentrations and temperatures studied, all normalized ECs fall on one curve. The EC activation energy was analyzed as a function of ammonia concentration and temperature.
引用
收藏
页码:277 / 279
页数:3
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