2-Dimensional Transition Metal Dichalcogenides with Tunable Direct Band Gaps: MoS2(1-x)Se2x Monolayers

被引:337
|
作者
Mann, John [1 ]
Ma, Quan [1 ]
Odenthal, Patrick M. [1 ]
Isarraraz, Miguel [1 ]
Le, Duy [2 ]
Preciado, Edwin [1 ]
Barroso, David [1 ]
Yamaguchi, Koichi [1 ]
Palacio, Gretel von Son [1 ]
Andrew Nguyen [1 ]
Tai Tran [1 ]
Wurch, Michelle [1 ]
Ariana Nguyen [1 ]
Klee, Velveth [1 ]
Bobek, Sarah [1 ]
Sun, Dezheng [1 ,3 ,4 ]
Heinz, Tony F. [3 ,4 ]
Rahman, Talat S. [2 ]
Kawakami, Roland [1 ]
Bartels, Ludwig [1 ]
机构
[1] Univ Calif Riverside, Riverside, CA 92521 USA
[2] Univ Cent Florida, Dept Phys, Orlando, FL 32816 USA
[3] Columbia Univ, Dept Phys, New York, NY USA
[4] Columbia Univ, Dept Elect Engn, New York, NY USA
基金
美国国家科学基金会;
关键词
molybdenum disulfide; molybdenum diselenide; transition metal dichalcogenides; CVD; alloys; bandgap engineering; atomically thin films; MOS2 ATOMIC LAYERS; LARGE-AREA; VALLEY POLARIZATION; GROWTH; PHOTOLUMINESCENCE; GRAPHENE; FILMS;
D O I
10.1002/adma.201304389
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MoS2(1-x) Se2x single-layer films are prepared using a mixture of organic selenium and sulfur precursors as well as a solid molybdenum source. The direct bandgaps are found to scale nearly linearly with composition in the range of 1.87 eV (pure single-layer MoS2) to 1.55 eV (pure single-layer MoSe2) permitting straightforward bandgap engineering. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1399 / 1404
页数:6
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