Structural relaxation of dense suspensions of soft giant micelles

被引:35
|
作者
Sigel, R
Pispas, S
Vlassopoulos, D
Hadjichristidis, N
Fytas, G
机构
[1] Inst Elect Struct & Laser, FORTH, GR-71110 Iraklion, Greece
[2] Univ Athens, Dept Chem, GR-15771 Athens, Greece
[3] Max Planck Inst Polymer Res, D-55021 Mainz, Germany
关键词
D O I
10.1103/PhysRevLett.83.4666
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The dynamics of liquid-like ordered giant colloidal micelles in the wave vector range around the peak of the structure factor is explored using photon correlation spectroscopy. No thermodynamic slowing down of the collective density fluctuations is found, whereas the long-time diffusion coefficient follows the concentration dependence of the suspension viscosity. Polymer-layer mediated effects are proposed to govern the physics of this unexpected behavior.
引用
收藏
页码:4666 / 4669
页数:4
相关论文
共 50 条
  • [1] Structural origin of relaxation in dense colloidal suspensions
    Sahu, Ratimanasee
    Sharma, Mohit
    Schall, Peter
    Bhattacharyya, Sarika Maitra
    Chikkadi, Vijayakumar
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2024, 121 (42)
  • [2] Linear and nonlinear rheology and structural relaxation in dense glassy and jammed soft repulsive pNIPAM microgel suspensions
    Ghosh, Ashesh
    Chaudhary, Gaurav
    Kang, Jin Gu
    Braun, Paul V.
    Ewoldt, Randy H.
    Schweizer, Kenneth S.
    SOFT MATTER, 2019, 15 (05) : 1038 - 1052
  • [3] Fracture and relaxation in dense cornstarch suspensions
    Lilin, Paul
    Elkhoury, Jean E.
    Peters, Ivo R.
    Bischofberger, Irmgard
    Ravichandran, Guruswami
    PNAS NEXUS, 2023, 3 (01):
  • [4] Relationship between particle elasticity, glass fragility, and structural relaxation in dense microgel suspensions
    Seekell, Raymond P.
    Sarangapani, Prasad S.
    Zhang, Zexin
    Zhu, Yingxi
    Soft Matter, 2015, 11 (27) : 5485 - 5491
  • [5] Relaxation times and rheology in dense athermal suspensions
    Olsson, Peter
    PHYSICAL REVIEW E, 2015, 91 (06):
  • [6] Modeling stress relaxation in dense, fine-particle suspensions
    Baumgarten, Aaron S.
    Kamrin, Ken
    JOURNAL OF RHEOLOGY, 2020, 64 (02) : 367 - 377
  • [7] Characteristics of the secondary relaxation process in soft colloidal suspensions
    Saha, Debasish
    Joshi, Yogesh M.
    Bandyopadhyay, Ranjini
    EPL, 2015, 112 (04)
  • [8] Dynamics of dense suspensions of star-like micelles with responsive fixed cores
    Loppinet, B
    Fytas, G
    Vlassopoulos, D
    Likos, CN
    Meier, G
    Liu, GJ
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (01) : 163 - 172
  • [9] Rheology of Dense Suspensions: Insights from Soft Dynamics Simulations
    Rognon, P.
    Gay, C.
    Einav, I.
    POWDERS AND GRAINS 2013, 2013, 1542 : 1090 - 1093
  • [10] STRUCTURAL ACOUSTIC RELAXATION IN SUSPENSIONS OF INTERACTING PARTICLES
    KOLTSOVA, IS
    MIKHAILOV, IG
    TROFIMOV, GS
    SOVIET PHYSICS ACOUSTICS-USSR, 1980, 26 (04): : 319 - 322