Synthesis of Novel Diselenide-Linked Porphyrin Dimers under Phase-Transfer Catalysis Condition and Their Interactions with DNA

被引：6

作者：

Xue, Zhi ^{[1
]}

Kwong, Daniel Wei-Jing ^{[2
]}

Xue, Ling-Wei ^{[3
]}

Liu, Qing ^{[1
]}

Hou, An-Xin ^{[1
]}

Wong, Wai-Kwok ^{[1
,2
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

[3] Pingdingshan Univ, Coll Chem & Chem Engn, Pingdingshan 467002, Peoples R China

来源：

CHEMISTRY & BIODIVERSITY | 2009年 / 6卷 / 07期

关键词：

DIPHENYL DISELENIDE; CATIONIC PORPHYRINS; CANCER PREVENTION; SELENIUM; ANTIBACTERIAL; PHOTOCLEAVAGE; COMBINATION; COMPLEXES; MECHANISM; POSITION;

D O I：

10.1002/cbdv.200800182

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Novel diselenide-linked porphyrin dimers were synthesized under phase-transfer catalysis conditions. The targeted compounds were characterized by H-1-NMR, high-resolution mass spectrometry, UV/VIS and fluorescence spectroscopies, redox-potential measurements, and elemental analysis. The interaction of the title compounds with DNA was studied using UV/VIS, fluorescence, and circular dichroism (CD) spectroscopies. The relative rates of singlet-oxygen production from the diselenide-linked porphyrin dimers upon photoirradiation were also measured.

引用

页码：1131 / 1143

页数：13

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