Carbon atoms trapped in cages: Metal carbide clusterfullerenes

被引：69
|
作者：
Jin, Peng [1 ]
Tang, Chengchun [1 ]
Chen, Zhongfang [2 ]
机构：
[1] Hebei Univ Technol, Sch Mat Sci & Engn, Tianjin 300130, Peoples R China
[2] Univ Puerto Rico, Inst Funct Nanomat, Dept Chem, San Juan, PR 00931 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2014年 / 270卷
关键词：
Fullerenes; Endohedral metallofullerenes; Clusters; DENSITY-FUNCTIONAL THEORY; ENDOHEDRAL DIMETALLOFULLERENES SC-2-AT-C-84; ULTRAVIOLET PHOTOELECTRON-SPECTRA; C-13; NMR; FULLERENE CAGE; STRUCTURAL-CHARACTERIZATION; ELECTRONIC-PROPERTIES; CRYSTALLOGRAPHIC CHARACTERIZATION; CLUSTER METALLOFULLERENES; SPECTROSCOPIC PROPERTIES;
D O I：
10.1016/j.ccr.2013.10.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal carbide clusterfullerenes (MCCFs), which trap two carbon atoms together with metal atom(s) inside the fullerene cage, are a novel branch of endohedral metallofullerenes (EMFs). This review presents an exhaustive survey of recent research progress in MCCFs. After a detailed enumeration of the structural establishments of representative MCCFs, their novel structures, intriguing cluster-cage interplays, fascinating properties, and potential applications are highlighted. Moreover, a variety of new MCCF members are suggested for future identification. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：89 / 111
页数：23
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