Radical copolymerization of 2-methoxy-4-formylphenyl (meth)acrylates with L-(-)-menthyl (meth)acrylates

被引:1
|
作者
Abdyev, O. B. [1 ]
Mamedbeili, E. G. [2 ]
机构
[1] Azerbaijan Natl Acad Sci, Inst Polymer Mat, AZ-5004 Sumgait, Azerbaijan
[2] Azerbaijan Natl Acad Sci, Inst Petrochem Proc, AZ-1025 Baku, Azerbaijan
关键词
OPTICALLY-ACTIVE POLYMERS; POLYMERIZATION; METHACRYLATE;
D O I
10.1134/S1560090414020018
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The radical copolymerization of 2-methoxy-4-formylphenyl (meth)acrylates with L-(-)-menthyl (meth)acrylates has been studied, and the reactivity ratios have been determined. It has been found that the bulk copolymerization of these monomers% results in insoluble copolymers when the content of 2-methoxy-4-formylphenyl (meth)acrylates in the pristine mixture exceeds 36 mol % and conversion exceeds similar to 30%. However, in the course of this reaction, soluble copolymers are formed in solution.
引用
收藏
页码:127 / 131
页数:5
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