A mild method for eliminating alkyl ethers to alkenes

被引:0
|
作者
Lindnera, Stephanie [1 ]
Braese, Stefan [1 ,2 ]
机构
[1] Karlsruhe Inst Technol, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Inst Toxicol & Genet, D-76344 Eggenstein Leopoldshafen, Germany
来源
RSC ADVANCES | 2014年 / 4卷 / 56期
关键词
1,2-DIHYDRONAPHTHALENE; ANHYDRIDE;
D O I
10.1039/c4ra03785e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A method for the conversion of methyl ethers into alkenes is described. In a one-step and mild procedure, both conjugated and isolated cyclic alkenes are accessible in mostly good yields using triflic anhydride in combination with triethylamine. This elimination procedure can also be applied to ethyl and benzyl ethers.
引用
收藏
页码:29439 / 29442
页数:4
相关论文
共 50 条
  • [1] A Mild and Versatile Method for the Synthesis of Alkyl Ethers from Methoxymethyl Ethers and Application to the Preparation of Sterically Crowded Ethers
    Minamitsuji, Yutaka
    Kawaguchi, Atsuhisa
    Kubo, Ozora
    Ueyama, Yoshifumi
    Maegawa, Tomohiro
    Fujioka, Hiromichi
    ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (10) : 1861 - 1866
  • [2] A NEW METHOD FOR THE CONVERSION OF ALKYL-SILYL ETHERS INTO ALKYL BROMIDES UNDER MILD CONDITIONS
    BARTSCH, R
    STELZER, O
    SCHMUTZLER, R
    SYNTHESIS-STUTTGART, 1982, (04): : 326 - 329
  • [3] Mild Synthesis of Sterically Congested Alkyl Aryl Ethers
    Lindstedt, Erik
    Stridfeldt, Elin
    Olofsson, Berit
    ORGANIC LETTERS, 2016, 18 (17) : 4234 - 4237
  • [4] New synthetic method of alkyl perfluoroalkyl ethers
    Tamura, M
    Takubo, S
    Quan, HD
    Sekiya, A
    SYNLETT, 2000, (03) : 343 - 344
  • [5] A highly efficient and convenient method for the direct conversion of alkyl THP ethers into the corresponding alkyl benzyl ethers
    Suzuki, T
    Ohasi, K
    Oriyama, T
    SYNTHESIS-STUTTGART, 1999, (09): : 1561 - 1563
  • [6] Rapid and Mild Cleavage of Aryl-Alkyl Ethers to Liberate Phenols
    Torrens, Aidan A.
    Ly, Alexandra L.
    Fong, Darryl
    Adronov, Alex
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 2022 (27)
  • [7] A mild and efficient procedure for the synthesis of ethers from various alkyl halides
    Kazemi, Mosstafa
    Noori, Zahra
    Kohzadi, Homa
    Sayadi, Mohsen
    Kazemi, Amin
    IRANIAN CHEMICAL COMMUNICATION, 2013, 1 (01) : 43 - 50
  • [8] A MILD METHOD FOR THE CONVERSION OF ALCOHOLS TO METHYLTHIOMETHYL ETHERS
    MEDINA, JC
    SALOMON, M
    KYLER, KS
    TETRAHEDRON LETTERS, 1988, 29 (31) : 3773 - 3776
  • [9] ALKYL ETHERS
    LOPIEKES, DV
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1966, 11 (04): : 581 - &
  • [10] An efficient and convenient method for the direct conversion of alkyl silyl ethers into the corresponding alkyl ethers catalyzed by iron(III) chloride
    Iwanami, K
    Yano, K
    Oriyama, T
    SYNTHESIS-STUTTGART, 2005, (16): : 2669 - 2672