Solvent Transport Characteristics of Thermoplastic Elastomer Blends Based on Nylon and NBR

被引：13
|
作者：
Abraham, Jiji [1 ]
Muraleedharan, K. [1 ]
Kumar, C. Radhesh [1 ]
Thomas, Sabu [1 ]
George, Soney C. [2 ]
机构：
[1] Mahatma Gandhi Univ, Int & Inter Univ Ctr Nanosci & Nanotechnol, Kottayam 686560, Kerala, India
[2] Amal Jyothi Coll Engn, Ctr Nanosci & Nanotechnol, Kottayam, Kerala, India
来源：
POLYMER ENGINEERING AND SCIENCE | 2017年 / 57卷 / 02期
关键词：
RUBBER BLENDS; MECHANICAL-PROPERTIES; DENSITY POLYETHYLENE; RHEOLOGICAL BEHAVIOR; MOLECULAR-TRANSPORT; NATURAL-RUBBER; MELT RHEOLOGY; MORPHOLOGY; DIFFUSION; MEMBRANES;
D O I：
10.1002/pen.24409
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Transport characteristics of chlorinated hydrocarbon through Nylon/NBR (Acrylonitrile Butadiene Rubber) blend has been investigated with special reference to the effect of blend ratio, compatibilizer and effect of dynamic crosslinking. An attempt has been made to correlate the diffusion characteristics with morphology of the blend. Fine and uniform distribution of the dispersed domains with a stable morphology were obtained by dynamic vulcanization. Depending on the composition, blends show dispersed/matrix and co-continuous phase morphologies. The various transport parameters such as diffusion coefficient (D), permeation coefficient (P) and sorption coefficients (S) were evaluated at different diffusion conditions such as temperature and percentage of compatibilizer. The equilibrium solvent uptake decreases with an increase in the concentration of NBR in the blends. Finally thermodynamic parameters were evaluated from the diffusion data. POLYM. ENG. SCI., 57: 231-236, 2017. (C) 2016 Society of Plastics Engineers.
引用
收藏
页码：231 / 236
页数：6
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