Regioselective ring opening of epoxides by nucleophiles mediated by lithium bistrifluoromethanesulfonimide

被引：92
|
作者：
Cossy, J
Bellosta, W
Hamior, C
Desmurs, JR
机构：
[1] ESPCI, CNRS, Chim Organ Lab, F-75231 Paris 05, France
[2] Rhodia, F-69457 Lyon, France
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 39期
关键词：
epoxides; nucleophiles; ring opening;
D O I：
10.1016/S0040-4039(02)01533-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the presence of LiNTf2, epoxides undergo ring opening with high regioselectivity and in good yield when they are treated with nucleophiles such as amines, hydrazines and thiophenol. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7083 / 7086
页数：4
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