Synthesis of organosoluble and fluorescent aromatic polyketones bearing 1,1'-binaphthyl units through Suzuki-Miyaura coupling polymerization

被引：7

作者：

Maeyama, Katsuya ^{[1
]}

Tsukamoto, Tadashi ^{[1
]}

Kumagai, Hiroaki ^{[1
]}

Higashibayashi, Shuhei ^{[2
]}

Sakurai, Hidehiro ^{[3
]}

机构：

[1] Yamagata Univ, Grad Sch Sci & Engn, Dept Polymer Sci & Engn, Yonezawa, Yamagata 9928510, Japan

[2] Res Ctr Integrat Mol Syst, Inst Mol Sci, Okazaki, Aichi 4448787, Japan

[3] Osaka Univ, Grad Sch Engn, Div Appl Chem, Suita, Osaka 5650871, Japan

来源：

POLYMER BULLETIN | 2015年 / 72卷 / 11期

关键词：

Suzuki-Miyaura coupling polymerization; Nanosized palladium clusters; Aromatic polyketones; Binaphthyls; Fluorescent polymers; POLY(ETHER KETONE)S; REGIOSELECTIVE CYCLOTRIMERIZATION; ETHER)S;

D O I：

10.1007/s00289-015-1443-z

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanosized palladium cluster-catalyzed Suzuki-Miyaura coupling polymerization of 1,1'-binaphthyldiyl-bearing diiodides with expanded pi-conjugated aromatic diboronic acid pinacol diesters affords aromatic polyketones, which have blue-emitting fluorescent properties (lambda (em) 450-489 nm) in addition to high thermal stability (T (g) 190-297 A degrees C) and excellent solubility in common organic solvents such as DMSO and NMP.

引用

页码：2903 / 2916

页数：14

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