Desulfurization of thiophene in alkaline supercritical water studied by 1H and 13C NMR

被引：10

作者：

Yoshida, S

Takewaki, K

Miwa, K

Wakai, C

Nakahara, M ^{[1
]}

机构：

[1] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

[2] Ishikawajima Harima Heavy Ind Co Ltd, Environm Proc Dev Dept, Ind Machine & Plant Dev Ctr, Isogo Ku, Yokohama, Kanagawa 2358501, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 03期

关键词：

D O I：

10.1246/cl.2004.330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thiophene, which is one of the major sulfur-containing compounds in crude oil as well as dibenzothiophene, was successfully desulfurized by the heterolytic cleavage of the C-S-C bond through the treatment with NaOH in supercritical water at 400degreesC. Thiophene was disintegrated into S2- and such carboxylic acids as formic, acetic, and succinic acids within I h.

引用

页码：330 / 331

页数：2

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