Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings

被引：301

作者：

Gildner, Peter G. ^{[1
]}

Colacot, Thomas J. ^{[1
]}

机构：

[1] Johnson Matthey Catalysis & Chiral Technol, W Deptford, NJ 08066 USA

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 23期

关键词：

HETEROCYCLIC CARBENE COMPLEXES; DEACTIVATED ARYL CHLORIDES; LARGE-SCALE APPLICATIONS; HIGHLY-ACTIVE CATALYST; AIR-STABLE CATALYSTS; ROOM-TEMPERATURE; SUZUKI-MIYAURA; ALPHA-ARYLATION; C-N; GENERAL-METHOD;

D O I：

10.1021/acs.organomet.5b00567

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A brief account of the major developments of palladium-catalyzed cross-coupling during the last two decades is highlighted chronologically, with an emphasis on the personal experiences of the corresponding author. Important contributions from both academia and industry, which have been vital to the accelerated growth of this area, are presented. The developments of new classes of ligands and the switch from in situ to preformed catalysts tailored to address the challenges in cross-coupling are reviewed, reflecting an evolution in continued growth.

引用

页码：5497 / 5508

页数：12

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