In this paper we study the higher secant varieties of Grassmarm varieties in relation to the functional Waring's problem for alternating tensors and to the Alexander-Hirschowitz theorem. We show how to identify defective higher secant varieties of Grassmannians using a probabilistic method involving Terracini's lemma, and we describe an algorithm which can compute, by numerical methods, dim (S(s)G(k, n)) for n <= 14. Our main result is that, except for Grassmannians of lines, if n <= 14 and k <= n-1/2 (if n = 14 we have studied the case k <= 5) there are only the four known defective cases: S(2)G (2, 6), S2G (3, 7), S-3 G (3, 7) and S'G (2, 8). (c) 2006 Elsevier Inc. All rights reserved.