Non-classical effects in proton or hydrogen transfer

Results of thorough investigations of tautomerism in the ground and excited electronic states performed for various organic molecules under different regimes: condensed phases, isolated and single molecules, with a special emphasis on porphycene, a porphyrin isomer, demonstrate that, in order to precisely describe the proton/hydrogen transfer path, one has to explicitly consider tunneling. Tautomerization is a multidimensional process, controlled by excitation of specific vibrational modes. Vibrational excitation can both enhance or hinder the reaction. The role of specific vibrational modes can now be assessed, even at the level of single molecules.