Experimental evidence for the p-d hybridization in the Cd-Ca quasicrystal:: Origin of the pseudogap -: art. no. 146402

被引:19
|
作者
Tamura, R [1 ]
Takeuchi, T
Aoki, C
Takeuchi, S
Kiss, T
Yokoya, T
Shin, S
机构
[1] Tokyo Univ Sci, Dept Mat Sci & Technol, Chiba 2788510, Japan
[2] Nagoya Univ, Res Ctr Adv Waste & Emiss Management, Nagoya, Aichi 4648603, Japan
[3] Univ Tokyo, ISSP, Chiba 2778581, Japan
关键词
D O I
10.1103/PhysRevLett.92.146402
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Ca 2p-3d resonant photoemission spectroscopy of a Cd6Ca crystalline approximant unambiguously demonstrates that the low-lying unoccupied 3d levels of calcium are lowered below the Fermi energy by the formation of the approximant, as suggested from electronic structure calculations [Y Ishii and T Fujiwara, Phys. Rev. Lett. 87, 206408 (2001)]. Moreover, the Ca 3d partial density of states (DOS) obtained near the Fermi energy is in reasonable agreement with theoretical Ca 3d DOS. These results verify the unconventional Picture that the origin of the pseudogap in the Cd-based quasicrystals is due to hybridization of the Ca 3d band with the Cd 5p band.
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页码:146402 / 1
页数:4
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