Immobilization of a binuclear ruthenium(III) complex on a gold (111) surface: Observations of proton-coupled electron transfer and electrochemical durability in aqueous media

被引：13
|
作者：
Uehara, Hiromitsu
Abe, Masaaki [1 ]
Hisaeda, Yoshio
Uosaki, Kohei
Sasaki, Yoichi
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan
[2] Kyushu Univ, Grad Sch Engn, Dept Appl Chem, Nishi Ku, Fukuoka 8190395, Japan
来源：
CHEMISTRY LETTERS | 2006年 / 35卷 / 10期
关键词：
D O I：
10.1246/cl.2006.1178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2-12) with remarkable monolayer durability for multiple potential cycles.
引用
收藏
页码：1178 / 1179
页数：2
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