Metal-organic frameworks' tricks in asymmetric catalysis

被引：9

作者：

Guo, Jun ^{[1
]}

Lian, Ye ^{[1
]}

Li, Fangfang ^{[1
]}

Duan, Yulong ^{[1
]}

Xue, Xiaomin ^{[1
]}

Long, Chang ^{[2
,3
]}

Zhang, Yin ^{[2
,3
]}

Tang, Zhiyong ^{[2
,3
]}

机构：

[1] Tiangong Univ, Sch Chem, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China

[2] Natl Ctr Nanosci & Technol, CAS Ctr Excellence Nanosci, CAS Key Lab Nanosyst & Hierarch Fabricat, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

CHEM CATALYSIS | 2022年 / 2卷 / 11期

基金：

国家重点研发计划; 中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE RECOGNITION; HETEROGENEOUS CATALYST; SPONTANEOUS RESOLUTION; COOPERATIVE CATALYSIS; COORDINATION POLYMER; MICHAEL ADDITION; CHIRAL CATALYSTS; ORGANOCATALYST; CONFINEMENT; SEPARATION;

D O I：

10.1016/j.checat.2022.09.024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymmetric catalysis plays an irreplaceable role in the fields of pharmaceuticals, biomaterials, pesticides, and chiral optics. Due to the lessons from the specific catalysis occurring inside enzyme pockets, chiral metal- organic frameworks (CMOFs) are conceived as promising candidates for subtly modulating asymmetric catalysis performances. In this review, we first discuss an overview of the design and construction strategies of CMOFs that are essential to discern their versatile tricks in asymmetric catalysis. More importantly, a thoughtful discussion concerning CMOFs' tricks in performance regulations of asymmetric catalysis is presented, including chiral pore environment decoration, metal node variation, crystal phase controlment, and nanostructure engineering. In addition, challenges and opportunities in this fundamental and cutting-edge research are also provided based on our own perspectives to attract more research interests and efforts in the future.

引用

页码：2986 / 3018

页数：33

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