Tunable Prussian blue analogues for the selective synthesis of propargylamines through A3 coupling

被引：27
|
作者：
Marquez, Carlos [1 ]
Cirujano, Francisco G. [1 ]
Van Goethem, Cedric [1 ]
Vankelecom, Ivo [1 ]
De Vos, Dirk [1 ]
De Baerdemaeker, Trees [1 ]
机构：
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F, B-3001 Leuven, Belgium
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2018年 / 8卷 / 08期
关键词：
METAL CYANIDE CATALYSTS; HETEROGENEOUS CATALYST; EFFICIENT; ALKYNE; ALDEHYDE; LIGAND; TRIMETHYLSILYLACETYLENE; POLYMERIZATION; INDOLIZINES; CYCLIZATION;
D O I：
10.1039/c8cy00073e
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
M1[Co(CN)6]2/3-type Prussian blue analogues (M1-Co PBAs) were studied as catalysts for the synthesis of propargylamines via A3 coupling of phenylacetylene, benzaldehyde and piperidine. Cu0.86Zn0.14-Co PBA was the best catalyst for the reaction by combining the high conversion obtained with Cu-Co PBA with the excellent selectivity obtained with Zn-Co PBA. © 2018 The Royal Society of Chemistry.
引用
收藏
页码：2061 / 2065
页数：5
相关论文
共 50 条
  • [1] Metal ion exchange in Prussian blue analogues: Cu(ii)-exchanged Zn-Co PBAs as highly selective catalysts for A3 coupling
    Marquez, Carlos
    Cirujano, Francisco G.
    Smolders, Simon
    Van Goethem, Cedric
    Vankelecom, Ivo
    De Vos, Dirk
    De Baerdemaeker, Trees
    DALTON TRANSACTIONS, 2019, 48 (12) : 3946 - 3954
  • [2] Strategies for synthesis of Prussian blue analogues
    Kjeldgaard, Solveig
    Dugulan, Iulian
    Mamakhel, Aref
    Wagemaker, Marnix
    Iversen, Bo Brummerstedt
    Bentien, Anders
    ROYAL SOCIETY OPEN SCIENCE, 2021, 8 (01):
  • [3] Highly efficient, iodide catalysed propargylamines synthesis via A3 coupling reaction
    Singh, Ashmita
    Narula, Anudeep Kumar
    RESULTS IN CHEMISTRY, 2022, 4
  • [4] Recent advances in Prussian blue and Prussian blue analogues: synthesis and thermal treatments
    Zakaria, Mohamed B.
    Chikyow, Toyohiro
    COORDINATION CHEMISTRY REVIEWS, 2017, 352 : 328 - 345
  • [5] Catalysts for Propargylamines Synthesis via A3, AHA, and KA2 Coupling - A Review
    Berrichi, Amina
    Bachir, Redouane
    Bedrane, Sumeya
    CURRENT ORGANIC CHEMISTRY, 2023, 27 (07) : 621 - 643
  • [6] Exchange coupling in an electrodeposited magnetic bilayer of Prussian blue analogues
    Prieto-Ruiz, Juan P.
    Romero, Francisco M.
    Prima-Garcia, Helena
    Coronado, Eugenio
    JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (42) : 11122 - 11128
  • [7] Design and Synthesis of Concentration Gradient Prussian Blue Analogues
    Jeon, SuKyung
    Li, Carissa H.
    Talham, Daniel R.
    CRYSTAL GROWTH & DESIGN, 2021, 21 (02) : 916 - 925
  • [8] An Efficient Catalytic System Based on CuI and Ionic Liquid for the Synthesis of Propargylamines Through One-Pot A3 Coupling Reactions
    Anlian Zhu
    Jingyi Wang
    Mingyue Wang
    Dongshuang Fan
    Lingjun Li
    Catalysis Letters, 2023, 153 : 2074 - 2082
  • [9] A novel route to synthesize lavendamycin analogues through an A3 coupling reaction
    Ramesh, Subburethinam
    Nagarajan, Rajagopal
    TETRAHEDRON, 2013, 69 (24) : 4890 - 4898
  • [10] Prussian Blue Analogues: A Versatile Framework for Solid-Contact Ion-Selective Electrodes with Tunable Potentials
    Klink, Stefan
    Ishige, Yu
    Schuhmann, Wolfgang
    CHEMELECTROCHEM, 2017, 4 (03): : 490 - 494
12345