Synthesis of triphenylmethylphosphonium chlorochoromate as a mild and selective reagent for oxidation of alcohols

被引：13
|
作者：
Hajipour, A. R. [1 ]
Khazdooz, L.
Ruoho, A. E.
机构：
[1] Isfahan Univ Technol, Coll Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2005年 / 2卷 / 04期
关键词：
alcohols; aldehydes; ketones; oxidation; triphenylmethylphosphonium chlorochoromate;
D O I：
10.1007/BF03245936
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triphenylmethylphosphonium chlorochoromate was synthesized from triphenylmethyl bromide and chromium( VI) oxide in HCl 6 N and used as an efficient and selective reagent for oxidation of alcohols to their corresponding aldehydes or ketones derivatives in refluxing acetonitrile in good to excellent yields.
引用
收藏
页码：315 / 318
页数：4
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