Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

被引：21
|
作者：
Hussein, Lenard [1 ]
Purkait, Nibadita [1 ]
Biyikal, Mustafa [1 ]
Tausch, Eugenia [2 ]
Roesky, Peter W. [2 ]
Blechert, Siegfried [1 ]
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[2] Karlsruher Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 29期
关键词：
ASYMMETRIC HYDROAMINATION; COMPLEXES; ZIRCONIUM; ALKENES;
D O I：
10.1039/c3cc48874h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New bimetallic Zn/Zr salen-type systems were employed as catalysts in the asymmetric intramolecular hydroamination reaction. High enantio-selectivity for the formation of piperidines of up to 98% ee were observed.
引用
收藏
页码：3862 / 3864
页数：3
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