Self-assembled monolayers of non-heme diiron(III) model complexes on Au(111) electrode: Synthesis and proton-coupled redox behavior in water

被引：13

作者：

Inomata, T ^{[1
]}

Abe, M ^{[1
]}

Kondo, T ^{[1
]}

Umakoshi, K ^{[1
]}

Uosaki, K ^{[1
]}

Sasaki, Y ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled monolayers (SAMs) of non-heme diiron(III) biomimetic complexes have been prepared on Au(lll) electrode surfaces to explore redox properties of diiron centers in aqueous solution in a wide pH range. The diiron(III) SAMs exhibited the proton-coupled electron-transfer reaction (1H(+)/1e(-)) in water.

引用

页码：1097 / 1098

页数：2

共 7 条

[1] Synthesis and electrochemical characterization of self-assembled monolayers of redox-active oxide-bridged triruthenium(III) clusters on Au(111)
Abe, M
Kondo, T
Uosaki, K
Sasaki, Y
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 473 (1-2) : 93 - 98
[2] Scanning tunneling microscopy observations of proton and metal cation catching behavior of embedded bipyridine thiols in alkanethiol self-assembled monolayers on Au(111)
Ishida, Takao
Koyama, Emiko
Tokuhisa, Hideo
Nakamura, Tohru
Kanesato, Masatoshi
Mizutani, Wataru
Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2006, 45 (07): : 6028 - 6032
[3] Scanning tunneling microscopy observations of proton and metal cation catching behavior of embedded bipyridine thiols in alkanethiol self-assembled monolayers on Au(111)
Ishida, Takao
Koyama, Emiko
Tokuhisa, Hideo
Nakamura, Tohru
Kanesato, Masatoshi
Mizutani, Wataru
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (07): : 6028 - 6032
[4] Effects of electrolytes on the redox potential and the rate of the CO dissociation reaction of trinuclear ruthenium monocarbonyl complexes self-assembled on an Au(111) electrode surface
Michi, Takayuki
Abe, Masaaki
Matsuno, Junzo
Uosaki, Kohei
Sasaki, Yoichi
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (07) : 1368 - 1376
[5] Effects of electrolytes on the redox potential and the rate of the CO dissociation reaction of trinuclear ruthenium monocarbonyl complexes self-assembled on an Au(111) electrode surface
Michi, Takayuki
Abe, Masaaki
Matsuno, Junzo
Uosaki, Kohei
Sasaki, Yoichi
Bulletin of the Chemical Society of Japan, 2007, 80 (07): : 1368 - 1376
[6] Proton-Coupled Electron Transfer and Lewis Acid Recognition at Self-Assembled Monolayers of an Oxo-Bridged Diruthenium(III) Complex Functionalized with Two Disulfide Anchors
Zhang, Hua-Xin
Abe, Masaaki
Zhang, Yi
Li, Guofang
Ye, Shen
Osawa, Masatoshi
Sasaki, Yoichi
LANGMUIR, 2013, 29 (32) : 10110 - 10119
[7] Synthesis and proton-coupled electron-transfer reaction of self-assembled monolayers of a ruthenium(II) complex containing tridentate 2,6-bis(benzimidazol-2-yl)pyridine on a cold surface: Comparison of acid/base chemistry with bulk solution chemistry
Haga, H
Hong, HG
Shiozawa, Y
Kawata, Y
Monjushiro, H
Fukuo, T
Arakawa, R
INORGANIC CHEMISTRY, 2000, 39 (20) : 4566 - 4573

← 1 →