Lithium-ion induced conformational change of 5,17-bis(9-fluorenyl)-25,26,27,28-tetrapropoxy calix[4]arene resulting in an egg-shaped dimeric clathrate

被引：6

作者：

Faldt, A

Krebs, FC

Jorgensen, M

机构：

[1] Condensed Matter Phys & Chem Dept, Riso Natl Lab, DK-4000 Roskilde, Denmark

[2] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 08期

关键词：

supramolecular chemistry; calixarenes; inclusion; X-ray crystallography;

D O I：

10.1016/S0040-4039(99)02252-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Synthesis and structural investigation of a 5,17-bis(9-fluorenyl)-25,26,27,28-tetrapropoxy calix[4]arene and its lithium complex salt that forms a dimeric clathrate with a molecule of solvent inside a cavity. At least three different interactions were identified as being responsible for the formation of the egg-shaped supramolecular assembly. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1241 / 1244

页数：4