Solubility and thermodynamics of solvation of krypton in aqueous-methanol solutions of urea at 101 325 Pa and 278-318 K: I. Effect of H/D isotope substitution

被引：0

作者：

Abrosimov, V. K. ^{[1
]}

Ivanov, E. V. ^{[1
]}

Lebedeva, E. Yu. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Solut, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2006年 / 76卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

General Chemistry; Krypton; Isotope Substitution; Water Alcohol; Urea Content;

D O I：

10.1134/S1070363206050069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solubility of Kr in H2O-CD3OH-CO(NH2)(2) and D2O-CH3OD-CO(ND2)(2) mixtures in the entire range of compositions of the mixed aqueous-methanol solvent at a urea content of up to 1.5 solvomolality units (mole fraction 0.0263) was measured at 101 325 Pa and 278.15-318.15 K (at 10 K step). The standard Sechenov parameters K-S(0) of the solubility of Kr and the thermodynamic parameters of krypton-urea pair interactions were determined. A differentiating effect of the H/D isotope substitution on K-S(0) was revealed: Upon deuteration of groups participating in strong hydrogen bonding, the Sechenov solubility parameter increases, and upon replacement of CH3 by CD3, decreases in the absolute value.

引用

页码：700 / 704

页数：5

共 12 条

[1] Solubility and thermodynamics of solvation of krypton in aqueous-methanol solutions of urea at 101 325 Pa and 278–318 K: I. Effect of H/D isotope substitution
V. K. Abrosimov
E. V. Ivanov
E. Yu. Lebedeva
Russian Journal of General Chemistry, 2006, 76 : 700 - 704
[2] Solubility and thermodynamics of solvation of krypton in aqueous-methanol solutions of urea at 101325 Pa and 278-318 K
Abrosimov, VK
Ivanov, EV
Lebedeva, EY
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (07) : 1010 - 1016
[3] Solubility and Thermodynamics of Solvation of Krypton in Aqueous-Methanol Solutions of Urea at 101325 Pa and 278–318 K
V. K. Abrosimov
E. V. Ivanov
E. Yu. Lebedeva
Russian Journal of General Chemistry, 2005, 75 : 1010 - 1016
[4] Solubility and thermodynamics of solvation of krypton in mixtures of H/D isotopomers of water and methanol at 101325 Pa and 278-318 K
Ivanov, EV
Abrosimov, VK
Lebedeva, EY
Ivanova, NG
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2003, 73 (05) : 665 - 674
[5] Solubility and Thermodynamics of Solvation of Krypton in Mixtures of H/D Isotopomers of Water and Methanol at 101325 Pa and 278-318 K
E. V. Ivanov
V. K. Abrosimov
E. Yu. Lebedeva
N. G. Ivanova
Russian Journal of General Chemistry, 2003, 73 : 665 - 674
[6] Effect of H/D-isotope substitution on the solubility and solvation thermodynamics of krypton in methanol solutions of carbamide
E. V. Ivanov
N. G. Ivanova
V. K. Abrosimov
E. Yu. Lebedeva
Russian Chemical Bulletin, 2001, 50 : 2360 - 2365
[7] Effect of H/D-isotope substitution on the solubility and solvation thermodynamics of krypton in methanol solutions of carbamide
Ivanov, EV
Ivanova, NG
Abrosimov, VK
Lebedeva, EY
RUSSIAN CHEMICAL BULLETIN, 2001, 50 (12) : 2360 - 2365
[8] H/D Isotope Substitution Effect on the Structural and Thermodynamic Parameters of Intermolecular Interaction in Methanol at 278-318 K
E. V. Ivanov
V. K. Abrosimov
N. G. Ivanova
Journal of Structural Chemistry, 2000, 41 : 989 - 996
[9] H/D isotope substitution effect on the structural and thermodynamic parameters of intermolecular interaction in methanol at 278-318 K
Ivanov, EV
Abrosimov, VK
Ivanova, NG
JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (06) : 989 - 996
[10] Thermodynamics of H/D isotope effects of hydration of urea and structural features of its aqueous solutions at various temperatures: I. Volume properties of water-urea and heavy water-deuterated urea systems
Ivanov, EV
Abrosimov, VK
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2000, 70 (03) : 380 - 390

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