Application of polyantimonic acid-polyacrylonitrile for removal of strontium(II) from simulated high-level liquid waste

被引:9
|
作者
Ma, Fuyin [1 ,2 ,3 ]
Li, Zheng [1 ,3 ]
Zhou, Wei [1 ,3 ]
Li, Qingnuan [1 ,3 ]
Zhang, Lan [1 ,3 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Chinese Acad Sci, Key Lab Nucl Radiat & Nucl Energy Technol, Shanghai 201800, Peoples R China
基金
中国国家自然科学基金;
关键词
Polyantimonic acid-polyacrylonitrile; Simulated HLLW; Strontium(II); Adsorption; Removal; INORGANIC-ION-EXCHANGERS; COMPOSITE SORBENTS; EXTRACTION; SEPARATION; BEHAVIOR; CESIUM; RADIONUCLIDES; ACTINIDES; SOLVENT; BEADS;
D O I
10.1007/s10967-016-5150-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Applicability of polyantimonic acid-polyacrylonitrile (PAA-PAN) in 60-150 mesh for removal of strontium(II) from simulated high-level liquid waste (HLLW) was investigated in this paper. The adsorption behavior of Sr(II) and other typical fission products (FPs) onto PAA-PAN was determined by using batch experiments. The results show that PAA-PAN exhibited high adsorption affinity for Sr(II) in HNO3 medium, and other FPs except for Zr, which could be eluted by H2C2O4-HNO3, were weakly adsorbed on PAA-PAN. Then, a column experiment was performed to remove Sr(II) from simulated HLLW, and it's found that Sr(II) could be effectively transferred onto the PAA-PAN column from HLLW.
引用
收藏
页码:2007 / 2013
页数:7
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