Visualisation of axial chirality using H-2-{H-1} NMR in poly(gamma-benzyl L-glutamate), a chiral liquid crystal solvent

被引:7
|
作者
Smadja, W
Auffret, S
Berdague, P
Merlet, D
Canlet, C
Courtieu, J
Legros, JY
Boutros, A
Fiaud, JC
机构
[1] UNIV PARIS 11,INST CHIM MOL ORGAN,LAB CHIM STRUCT ORGAN,CNRS,URA 1384,F-91405 ORSAY,FRANCE
[2] UNIV PARIS 10,INST CHIM MOL ORGAN,LAB REACT ORGAN SELECT,CNRS,URA 1497,F-91405 ORSAY,FRANCE
关键词
D O I
10.1039/a705036d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Disubstituted, racemic, axially chiral compounds with true and isotopic chiralities have been discriminated through the differential ordering effect of enantiomers when dissolved in a chiral liquid crystal solvent made of organic solutions of poly(gamma-benzyl L-glutamate).
引用
收藏
页码:2031 / 2032
页数:2
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