Catalytic enantioselective oxidation of alkanes and alkenes using (salen)manganese complexes bearing a chiral binaphthyl strapping unit

被引：45
|
作者：
Murahashi, SI
Noji, S
Komiya, N
机构：
[1] Okayama Univ Sci, Dept Appl Chem, Okayama 7000005, Japan
[2] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 2-3期
关键词：
asymmetric epoxidation; asymmetric hydroxylation; C-H activation; hydrocarbons; iodosylbenzene; salen-manganese complex;
D O I：
10.1002/adsc.200303190
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A (salen)manganese (III) complex bearing a chiral binaphthyl strapping unit catalyzes the enantioselective hydroxylation of indane (up to 34% ee) and the epoxidation of alkenes (up to 93% ee) with iodosylbenzene.
引用
收藏
页码：195 / 198
页数：4
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