1,1,3,3-tetraoxo-1,2,3-triazapropene anion, a new oxy anion of nitrogen: The dinitramide anion and its salts

被引:124
|
作者
Bottaro, JC
Penwell, PE
Schmitt, RJ
机构
[1] Functionally Designed Mat. Program, Chem. and Chem. Eng. Laboratory, SRI International, Menlo Park, CA 94025
关键词
D O I
10.1021/ja9709278
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis of a completely new, stable class of inorganic salts named the dinitramide salts. These salts are based on a newly discovered nitrogen oxide anion known as the dinitramide anion. The dinitramide anion is a uniquely stable, high oxygen density grouping that can be prepared in many salt combinations including the ammonium or hydrazinium salts. The dinitramide anion has both fundamental scientific interest and practical applications. We describe here the synthesis of dinitramide salts and give a preliminary report on their properties.
引用
收藏
页码:9405 / 9410
页数:6
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