The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols

被引：78
|
作者：
Guo, Songjin [1 ]
Yu, Jin-Tao [1 ]
Dai, Qiang [1 ]
Yang, Haitao [1 ]
Cheng, Jiang [1 ,2 ]
机构：
[1] Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 47期
基金：
中国国家自然科学基金;
关键词：
METAL-FREE; CARBONYL-COMPOUNDS; BUTYL HYDROPEROXIDE; EFFICIENT SYNTHESIS; CARBOXYLIC-ACIDS; ESTERIFICATION; OXIDATION; ALDEHYDES; ESTERS; BENZOYLOXYLATION;
D O I：
10.1039/c4cc01652a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Bu4NI-catalyzed reaction of ketones with benzylic alcohols was achieved, leading to alfa-acyloxycarbonyl compounds in moderate to good yields. This metal-free procedure featured the employment of facilely and commercially available starting materials and TBHP as a clean oxidant with high atom economy.
引用
收藏
页码：6240 / 6242
页数：3
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