Study of the supramolecular interactions of carboxylic acids used as versatile ligands in coordination chemistry

被引：5
|
作者：
Corra, C. C. [1 ]
Scaldini, F. M. [2 ]
Machado, F. C. [2 ]
Pinheiro, C. B. [1 ]
机构：
[1] Univ Fed Minas Gerais, ICEX, Dept Fis, Belo Horizonte, MG, Brazil
[2] Univ Fed Juiz de Fora, ICE, Dept Quim, Juiz De Fora, MG, Brazil
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 06期
关键词：
supramolecular arrangement; carboxylate ligands; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; LUMINESCENT PROPERTY; POLYMERS; ABSORPTION; COMPLEXES; NETWORKS;
D O I：
10.1134/S0022476616060251
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Carboxylate ligands are very versatile because they can adopt different coordination modes towards metal cations, such as monodentate, bidentate-chelate, bidentate bridging and monoatomic bridging. Because of this versatility, these ligands have been widely used in coordination chemistry. In this study the three dimensional structure of the crystal arrangement of 2,5-thiophenedicarboxylic (H (2) TPD), trans-3-(3- pyridyl)acrylic (HPYA), and 4,4'-sulfonyldibenzoic (H (2) SFD) acids are determined in order to investigate their supramolecular properties for coordination polymers and metal-organic framework (MOF) constructions.
引用
收藏
页码：1235 / 1242
页数：8
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